Adhesive, adhesive layer, and adhesive sheet

ABSTRACT

A pressure-sensitive adhesive of the invention include a (meth)acryl-based polymer obtained by polymerization of a monomer component including 30 to 99.5% by weight of an alkyl (meth)acrylate having an alkyl group of 10 to 18 carbon atoms at an ester end and 0.5 to 50% by weight of a cyclic nitrogen-containing monomer. The pressure-sensitive adhesive has a satisfactory level of adhesive performance and can form a pressure-sensitive adhesive layer with a lower dielectric constant and reliable moisture resistance.

TECHNICAL FIELD

The invention relates to a pressure-sensitive adhesive capable have alower dielectric constant. The invention also relates to apressure-sensitive adhesive layer obtained from such apressure-sensitive adhesive and to a pressure-sensitive adhesive sheetincluding a support and such a pressure-sensitive adhesive layerprovided on at least one side of the support.

The pressure-sensitive adhesive layer or the pressure-sensitive adhesivesheet of the invention is suitable for use in optical applications. Forexample, the pressure-sensitive adhesive layer or the pressure-sensitiveadhesive sheet of the invention is suitable for use in the manufactureof image display devices such as liquid crystal display devices, organicelectro-luminescent (EL) display devices, plasma display panels (PDPs),and electronic paper, and is also suitable for use in the manufacture ofinput devices such as touch panels including optical, ultrasonic,capacitance, and resistive types. In particular, the pressure-sensitiveadhesive layer or the pressure-sensitive adhesive sheet of the inventionis advantageously used in capacitance touch panels.

The pressure-sensitive adhesive sheet of the invention is also useful asa pressure-sensitive adhesive optical member, in which an optical memberis used as the support. For example, when a transparent conductive filmis used as the optical member, the pressure-sensitive adhesive opticalmember can be used as a pressure-sensitive adhesive layer-carryingtransparent conductive film. Such a pressure-sensitive adhesivelayer-carrying transparent conductive film may be used as a transparentelectrode in the image display device or the touch panel mentioned aboveafter it is processed appropriately. In particular, thepressure-sensitive adhesive layer-carrying transparent conductive filmwith a patterned transparent conductive thin layer is advantageouslyused as an electrode substrate for an input device of a capacitancetouch panel. Additionally, the pressure-sensitive adhesivelayer-carrying transparent conductive film can be used forelectromagnetic wave shielding or prevention of static buildup ontransparent products and to form liquid crystal dimming glass productsand transparent heaters.

When an optical film is used as the optical member, thepressure-sensitive adhesive optical member can be used as apressure-sensitive adhesive layer-carrying optical film. Thepressure-sensitive adhesive layer-carrying optical film is used for animage display device such as a liquid crystal display device and anorganic electroluminescence (EL) display device. The optical film may bea polarizing plate, a retardation plate, an optical compensation film, abrightness enhancement film, a laminate thereof, or the like.

BACKGROUND ART

In recent years, input devices having a combination of a touch panel andan image display device, such as cellular phones and portable musicplayers, have become popular. In particular, capacitance touch panelshave rapidly become popular because of their functionality.

There are now many known transparent conductive films for use in touchpanels, which include a laminate of a transparent plastic film substrateor a glass sheet and a transparent conductive thin layer (ITO layer). Atransparent conductive film can be laminated on any other member with apressure-sensitive adhesive layer interposed therebetween. Various typesof pressure-sensitive adhesive layers are proposed (Patent Document 1 to4).

When the transparent conductive film is used as an electrode substratefor a capacitance touch panel, the transparent conductive thin layerused is patterned. The transparent conductive film with the patternedtransparent conductive thin layer is laminated on another transparentconductive film or any other component with a pressure-sensitiveadhesive layer interposed therebetween to form a laminate to be used.These transparent conductive films are advantageously used for amulti-touch input device, which can be operated by touching it with twoor more fingers at the same time. Specifically, a capacitance touchpanel is designed to achieve sensing when the amount of change in outputsignal, which is generated at a position where the touch panel istouched with a finger or the like, exceeds a certain threshold value.

PRIOR ART DOCUMENTS Patent Documents

Patent Document 1: JP-A-2003-238915

Patent Document 2: JP-A-2003-342542

Patent Document 3: JP-A-2004-231723

Patent Document 4: JP-A-2002-363530

Patent Document 5: WO 2010/147047

SUMMARY OF THE INVENTION Problems to be Solved by the Invention

As mentioned above, the dielectric constant of a component or film usedto form a touch panel is an important value related to the response ofthe touch panel. On the other hand, now, as touch panels have becomepopular, they have been required to have higher performance, andtransparent conductive films or pressure-sensitive adhesive layers to beused as components thereof also have been required to have higherperformance, in which a reduction in thickness is one of therequirements. However, there is a problem in that simply reducing thethickness of a pressure-sensitive adhesive layer can change the designedcapacitance. Thus, there is a need to reduce the dielectric constant ofa pressure-sensitive adhesive layer without changing the capacitancevalue when the pressure-sensitive adhesive layer is reduced inthickness. In some cases, an air layer between a printed glass or filmand an optical film or an air layer above an LCD is filled with apressure-sensitive adhesive layer so that visibility can be improved. Onthe other hand, however, such a pressure-sensitive adhesive may cause amalfunction if having high dielectric constant. To prevent such amalfunction, adhesive layers are required to have lower dielectricconstant. In addition, the reduction in the dielectric constant of apressure-sensitive adhesive layer is also expected to improve theresponse speed or sensitivity of a touch panel. There is also a problemin that when a laminate including a transparent conductive film and aglass sheet laminated with a pressure-sensitive adhesive layerinterposed therebetween is exposed to humid conditions, thepressure-sensitive adhesive layer become clouded.

It is therefore an object of the invention to provide apressure-sensitive adhesive that has a satisfactory level of adhesiveperformance and can form a pressure-sensitive adhesive layer with alower dielectric constant and reliable moisture resistance.

It is another object of the invention to provide a pressure-sensitiveadhesive layer made from such a pressure-sensitive adhesive and toprovide a pressure-sensitive adhesive sheet having such apressure-sensitive adhesive layer.

Means for Solving the Problems

As a result of intense investigations to solve the problems, theinventors have made the invention, based on the finding that the objectsare achieved with a pressure-sensitive adhesive described below.

The invention relates to a pressure-sensitive adhesive, including a(meth)acryl-based polymer obtained by polymerization of a monomercomponent including 30 to 99.5% by weight of an alkyl (meth)acrylatehaving an alkyl group of 10 to 18 carbon atoms at an ester end and 0.5to 50% by weight of a cyclic nitrogen-containing monomer. In the alkyl(meth)acrylate having the alkyl group of 10 to 18 carbon atoms at theester, preferable alkyl group is a branched alkyl group. The alkyl(meth)acrylate having the alkyl group of 10 to 18 carbon atoms at theester is also preferably an alkyl methacrylate in view of a lowerdielectric constant, and is also preferably an alkyl methacrylate inview of productivity.

In the pressure-sensitive adhesive, the monomer component may furtherinclude 0.5% by weight or more of at least one functionalgroup-containing monomer selected from a carboxyl group-containingmonomer, a hydroxyl group-containing monomer, and a cyclic ethergroup-containing monomer.

In the pressure-sensitive adhesive, the monomer component may furtherinclude 0.5% or more by weight of at least one selected from an alkyl(meth)acrylate having an alkyl group of 1 to 9 carbon atoms at an esterend and an alkyl (meth)acrylate having a cyclic alkyl group at an esterend.

In the pressure-sensitive adhesive, the monomer component may furthercontain 3% or less by weight or less of a polyfunctional monomer.

In the pressure-sensitive adhesive, the pressure-sensitive adhesivepreferably further include 0.01 to 5 parts by weight of a crosslinkingagent based on 100 parts by weight of the (meth)acryl-based polymer.

The pressure-sensitive adhesive is preferably for use on an opticalmember.

The invention also relates to a pressure-sensitive adhesive layerobtained from the above pressure-sensitive adhesive.

The pressure-sensitive adhesive layer preferably has a relativedielectric constant of 3.5 or less at a frequency of 100 kHz.

The pressure-sensitive adhesive layer preferably has a gel fraction of20 to 98% by weight.

The pressure-sensitive adhesive layer preferably has a haze of 2% orless when having a thickness of 25 μm.

The pressure-sensitive adhesive layer preferably has a total lighttransmittance of 90% or more.

The pressure-sensitive adhesive layer is preferably for use on anoptical member.

The invention also relates to a pressure-sensitive adhesive sheetincluding: a support; and the above pressure-sensitive adhesive layerformed on at least one side of the support.

The pressure-sensitive adhesive sheet preferably has an adhesivestrength of 0.5 N/20 mm or more to alkali glass at a peel angle of 90°and a peel rate of 300 mm/minute.

The pressure-sensitive adhesive sheet is preferably for use on anoptical member. The pressure-sensitive adhesive sheet is preferably apressure-sensitive adhesive optical member including an optical memberas the support and the pressure-sensitive adhesive layer provided on atleast one side of the optical member.

Effect of the Invention

The (meth)acryl-based polymer as a main component of thepressure-sensitive adhesive of the invention is obtained bypolymerization of a monomer component including a predetermined amountof an alkyl (meth)acrylate having a relatively long chain alkyl groupand a cyclic nitrogen-containing monomer. The relatively long chainalkyl group and a nitrogen atom-containing cyclic structure in thepressure-sensitive adhesive of the invention is effective in forming apressure-sensitive adhesive layer with a lower dielectric constant and areliable moisture resistance, and in providing a satisfactory level ofadhesive performance. Also when an air layer is filled with apressure-sensitive adhesive layer, malfunctions can be prevented becauseof the low dielectric constant of the adhesive layer.

To lower the dielectric constant, it is said that the dipole moment ofthe molecule may be reduced, and the molar volume of the molecule may beincreased, according to the Clausius-Mossotti equation. The main monomerunit of the (meth)acryl-based polymer as a main component of thepressure-sensitive adhesive of the invention is derived from an alkyl(meth)acrylate having a relatively long chain alkyl group. The(meth)acryl-based polymer also has a copolymerized unit derived from amonomer having a nitrogen atom-containing cyclic structure. Thesefeatures are considered to reduce the dielectric constant. The nitrogenatom-containing cyclic structure can also produce cohesive andhydrophilic effects, which are considered to provide reliable moistureresistance.

For example, the pressure-sensitive adhesive layer of the invention canhave a relative dielectric constant as low as 3.5 or less at a frequencyof 100 kHz. This feature makes it possible to design capacitance touchpanels with no change in capacitance value even when thepressure-sensitive adhesive layer of the invention is reduced inthickness to form a transparent conductive film for use in capacitancetouch panels, and the pressure-sensitive adhesive layer satisfies areliable moisture resistance.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a view showing an example of a capacitance touch panelproduced using the pressure-sensitive adhesive layer or thepressure-sensitive adhesive sheet of the invention.

MODE FOR CARRYING OUT THE INVENTION

The pressure-sensitive adhesive of the invention contains a(meth)acryl-based polymer obtained by polymerization of a monomercomponent including 30 to 99.5% by weight of an alkyl (meth)acrylatehaving an alkyl group of 10 to 18 carbon atoms at an ester end and 0.5to 50% by weight of a cyclic nitrogen-containing monomer. As usedherein, the term “alkyl (meth)acrylate” refers to alkyl acrylate and/oralkyl methacrylate, and “(meth)” is used in the same meaning in thedescription.

The alkyl (meth)acrylate having an alkyl group of 10 to 18 carbon atomsat the ester end is preferably capable of forming a homopolymer having aglass transition temperature (Tg) of −80 to 0° C., more preferably −70to −10° C. If the Tg of the homopolymer is −80° C. or lower, thepressure-sensitive adhesive may have too low an elastic modulus atnormal temperature, which is not preferred. If the Tg of the homopolymeris higher than 0° C., the adhesive strength may be undesirably reduced.The Tg of the homopolymer is the value measured using TG-DTA. To achievelow dielectric constant and moderate elastic modulus, the alkyl grouphas 10 to 18 carbon atoms. Based on this, an alkyl (meth)acrylate havinga suitable alkyl group can be selected as needed depending on the methodof producing the (meth)acryl-based polymer. For example, when the(meth)acryl-based polymer is produced by solution polymerization or thelike, the alkyl group preferably has preferably 10 to 16 carbon atoms,more preferably 10 to 14 carbon atoms. When the (meth)acryl-basedpolymer is produced by radiation polymerization or the like, the alkylgroup preferably has 12 to 18 carbon atoms, more preferably 14 to 18carbon atoms. It should be noted that a straight-chain alkyl group or analkyl group of 9 or less carbon atoms is less effective in lowering thedielectric constant of the pressure-sensitive adhesive layer even thoughthe homopolymer of the corresponding alkyl (meth)acrylate has a Tg of−80 to 0° C.

Although the alkyl group of 10 to 18 carbon atoms in the alkyl(meth)acrylate to be used may be any of a linear chain and a branchedchain, the alkyl group is preferably a branched chain in view of forminga pressure-sensitive adhesive layer with a lower dielectric constant. Itis conceivable that when the long chain alkyl group of the alkylmethacrylate is a branched alkyl group, a molar volume of a molecule ofthe long-chain alkyl group was increased, and reduces a lower dipolemoment so that it can form a pressure-sensitive adhesive layer with agood balance between them.

Examples of the alkyl (meth)acrylate having a branched-alkyl group of 10to 18 carbon atoms at the ester end include isodecyl acrylate (10carbons, homopolymer Tg=−60° C., hereinafter, simply abbreviated as Tg),isodecyl methacrylate (10 carbons, homopolymer Tg=−41° C.), isomyristylacrylate (14 carbons, homopolymer Tg=−56° C.), isostearyl acrylate (18carbons, homopolymer Tg=−18° C.), 2-propylheptylacrylate, isoundecylacrylate, isododecyl acrylate, isotridecyl acrylate, isopentadecylacrylate, isohexadecyl acrylate, isoheptadecyl acrylate, andmethacrylate monomers corresponding to the above acrylates. Thesemonomers may be used alone or in combination of two or more.

Of the branched alkyl group of 10 to 18 carbon atoms, those having at-butyl group are preferable in consideration of particularly obtaininga pressure-sensitive adhesive with an increased molar volume, a lowereddipole moment, and a balance of both. An Example of the alkyl(meth)acrylate having a branched alkyl group of 10 to 18 carbon atoms,the alkyl group having t-butyl group, includes isostearyl acrylaterepresented by the following formula:

Also, as the alkyl (meth)acrylate having an alkyl group of 10 to 18carbon atoms at the ester end, alkyl methacrylate is more preferablethan alkyl acrylates in view of the effects of the pressure-sensitiveadhesive layer lowering of dielectric constant due to an increase inmolar volume and a reduction in dipole moment. It is conceivable thatwhen the long chain alkyl group of the alkyl methacrylate is a linearalkyl group, the alkyl methacrylate can also have a higher molar volumeand a lower dipole moment so that it can form a pressure-sensitiveadhesive layer with a good balance between them. On the other hand, thealkyl acrylate has higher compatibility with the cyclicnitrogen-containing monomer than the alkyl methacrylate. The alkylacrylate is preferable in that it can form a (meth)acryl-based polymerwith good transparency, and the (meth)acryl-based polymer is preferablein that it can produced with a shorter polymerization time and higherproductivity. Particularly when the (meth)acryl-based polymer isproduced by radiation polymerization, the alkyl acrylate is preferred.

Examples of the alkyl methacrylate having an alkyl group of 10 to 18carbon atoms at the ester end include lauryl methacrylate (12 carbonatoms, Tg=−65° C.), tridecyl methacrylate (13 carbon atoms, Tg=−40° C.),stearyl methacrylate (18 carbon atoms, Tg=38° C.), isodecyl methacrylate(10 carbon atoms, Tg=−41° C.), undecyl methacrylate (11 carbon atoms),tetradecyl methacrylate (14 carbon atoms), pentadecyl methacrylate (15carbon atoms), hexadecyl methacrylate (16 carbon atoms), heptadecylmethacrylate (17 carbon atoms), etc. These may be used singly or incombination of two or more.

As will be appreciated from the foregoing, the alkyl (meth)acrylatehaving an alkyl group of 10 to 18 carbon atoms at the ester end ispreferably an alkyl methacrylate having a branched alkyl group of 10 to18 carbon atoms at the ester end.

The content of the alkyl (meth)acrylate having an alkyl group of 10 to18 carbon atoms at the ester end is 30 to 99.5% by weight, preferably 32to 99.5% by weight, more preferably 35 to 99.5% by weight, furthermorepreferably 40 to 99.5% by weight, furthermore preferably 45 to 96% byweight, and furthermore preferably 65 to 95% by weight, based on thetotal weight of the monomer component used to form the (meth)acryl-basedpolymer. Use of 30% by weight or more of the alkyl (meth)acrylate ispreferable in view of lowering of dielectric constant, and use of 99.5%by weight or less thereof is preferable in view of maintaining adhesivestrength.

Any monomer having a cyclic nitrogen structure and an unsaturated doublebond-containing polymerizable functional group such as a (meth)acryloylgroup or a vinyl group may be used without restriction as the cyclicnitrogen-containing monomer. The cyclic nitrogen structure preferablyhas a nitrogen atom in the cyclic structure. Examples of the cyclicnitrogen-containing monomer include vinyl lactam monomers such asN-vinylpyrrolidone, N-vinyl-ε-caprolactam, and methylvinylpyrrolidone;and nitrogen-containing heterocyclic vinyl monomers such asvinylpyridine, vinylpiperidone, vinylpyrimidine, vinylpiperazine,vinylpyrazine, vinylpyrrole, vinylimidazole, vinyloxazole, andvinylmorpholine. The cyclic nitrogen-containing monomer may also be a(meth)acrylic monomer having a heterocyclic ring such as a morpholinering, a piperidine ring, a pyrrolidine ring, or a piperazine ring.Examples include N-acryloyl morpholine, N-acryloylpiperidine,N-methacryloyl piperidine, and N-acryloyl pyrrolidine. Among them, vinyllactam monomers are preferred, and N-vinylpyrrolidone is particularlypreferred, in view of dielectric constant and cohesiveness.

In the invention, the content of the cyclic nitrogen-containing monomeris from 0.5 to 50% by weight, preferably from 0.5 to 40% by weight, morepreferably from 0.5 to 30% by weight, based on the total weight of themonomer component used to form the (meth)acryl-based polymer. A cyclicnitrogen-containing monomer content of 0.5% by weight or more ispreferred in terms of lower dielectric constant and reliable moistureresistance. A cyclic nitrogen-containing monomer content of 50% byweight or less is preferred in terms of adhering strength improvement.

The monomer component used to form the (meth)acryl-based polymeraccording to the invention may further include at least one functionalgroup-containing monomer selected from a carboxyl group-containingmonomer, a hydroxyl group-containing monomer, and a cyclic ethergroup-containing monomer.

Any monomer having a carboxyl group and an unsaturated doublebond-containing polymerizable functional group such as a (meth)acryloylgroup or a vinyl group may be used without restriction as the carboxylgroup-containing monomer. Examples of the carboxyl group-containingmonomer include (meth)acrylic acid, carboxyethyl (meth)acrylate,carboxypentyl (meth)acrylate, itaconic acid, maleic acid, fumaric acid,crotonic acid, and isocrotonic acid. These may be used alone or in anycombination. Itaconic acid or maleic acid can be used in the form of ananhydride. Among these, acrylic acid and methacrylic acid are preferred,and acrylic acid is particularly preferred. In the invention, a carboxylgroup-containing monomer may be or may not be used as an optionalmonomer to produce the (meth)acryl-based polymer. An adhesive containinga (meth)acryl-based polymer obtained from a monomer composition free ofany carboxyl group-containing monomer can form a pressure-sensitiveadhesive layer with reduced ability to corrode metals, because theability to corrode metals would be due to any carboxyl group.

Any monomer having a hydroxyl group and an unsaturated doublebond-containing polymerizable functional group such as a (meth)acryloylgroup or a vinyl group may be used without restriction as the hydroxylgroup-containing monomer. Examples of the hydroxyl group-containingmonomer include hydroxyalkyl (meth)acrylate such as 2-hydroxybutyl(meth)acrylate, 3-hydroxypropyl (meth)acrylate, 4-hydroxybutyl(meth)acrylate, 6-hydroxyhexyl (meth)acrylate, 8-hydroxyoctyl(meth)acrylate, 10-hydroxydecyl (meth)acrylate, or 12-hydroxylauryl(meth)acrylate; and hydroxyalkylcycloalkane (meth)acrylate such as(4-hydroxymethylcyclohexyl)methyl (meth)acrylate. Other examples includehydroxyethyl(meth)acrylamide, allyl alcohol, 2-hydroxyethyl vinyl ether,4-hydroxybutyl vinyl ether, and diethylene glycol monovinyl ether. Thesemay be used alone or in any combination. Among them, hydroxyalkyl(meth)acrylate is preferred.

Any monomer having a cyclic ether group such as an epoxy group or anoxetane group and an unsaturated double bond-containing polymerizablefunctional group such as a (meth)acryloyl group or a vinyl group may beused without restriction as the cyclic ether group-containing monomer.Examples of the epoxy group-containing monomer include glycidyl(meth)acrylate, 3,4-epoxycyclohexylmethyl (meth)acrylate, and4-hydroxybutyl(meth)acrylate glycidyl ether. Examples of the oxetanegroup-containing monomer include 3-oxetanylmethyl (meth)acrylate,3-methyl-oxetanylmethyl (meth)acrylate, 3-ethyl-oxetanylmethyl(meth)acrylate, 3-butyl-oxetanylmethyl (meth)acrylate, and3-hexyl-oxetanylmethyl (meth)acrylate. These monomers may be used aloneor in any combination.

In the invention, the content of the functional group-containing monomeris preferably 0.5% or more, further preferably 0.8% or more used to formthe (meth)acryl-based polymer so that adhesive strength and cohesivestrength can be increased. If the content of the functionalgroup-containing monomer is too high, a hard pressure-sensitive adhesivelayer with a lower adhesive strength may be formed, and thepressure-sensitive adhesive may have too high a viscosity or may form agel. Thus, the content of the functional group-containing monomer ispreferably 30% by weight or less, more preferably 27% by weight or less,even more preferably 25% by weight or less based on the total weight ofthe monomer component used to form the (meth)acryl-based polymer.

The monomer component used to form the (meth)acryl-based polymeraccording to the invention may further include a copolymerizable monomerother than the functional group-containing monomer. For example, acopolymerizable monomer other than those described above may be an alkyl(meth)acrylate represented by the formula CH₂═C(R¹) COOR², wherein R¹represents hydrogen or a methyl group, and R² represents a substitutedor unsubstituted alkyl group of 1 to 9 carbon atoms.

The substituted or unsubstituted alkyl group of 1 to 9 carbon atomsrepresented by R² may be a linear or branched alkyl group or cyclicalkyl group. Specifically, R² represents a branched alkyl of group of 3to 9 carbon atoms. The substituted alkyl group preferably has an arylgroup of 3 to 8 carbon atoms or an aryloxy group of 3 to 8 carbon atomsas a substituent. The aryl group is preferably, but not limited to, aphenyl group. Concerning this alkyl (meth)acrylate, the alkylmethacrylate is more preferred than the alkyl acrylate in order to lowerdielectric constant by increasing molar volume and reducing dipolemoment.

Examples of the monomer represented by CH₂═C(R¹) COOR² include methyl(meth)acrylate, ethyl (meth)acrylate, n-butyl (meth)acrylate, sec-butyl(meth)acrylate, tert-butyl (meth)acrylate, isobutyl (meth)acrylate,n-pentyl (meth)acrylate, isopentyl (meth)acrylate, hexyl (meth)acrylate,heptyl (meth)acrylate, isoamyl (meth)acrylate, 2-ethylhexyl(meth)acrylate, n-octyl (meth)acrylate, isooctyl (meth)acrylate, n-nonyl(meth)acrylate, isononyl (meth)acrylate, phenoxyethyl (meth)acrylate,benzyl (meth)acrylate, cyclohexyl (meth)acrylate,3,3,5-trimethylcyclohexyl (meth)acrylate, and isobornyl (meth)acrylate.These monomers may be used alone or in any combination.

In the invention, the content of the (meth)acrylate represented byCH₂═C(R¹)COOR² may be 69.5% by weight or less, preferably 65% by weightor less, more preferably 59.5% by weight or less, even more preferably55% by weight or less, even more preferably 50% by weight or less, evenmore preferably 40% by weight or less, even more preferably 30% byweight or less, based on the total weight of the monomer component usedto form the (meth)acryl-based polymer. To maintain the level of adhesivestrength, the (meth)acrylate represented by CH₂═C(R¹)COOR² is preferablyused in an amount of 5% by weight or more, more preferably 10% by weightor more.

The preferred content of the (meth)acrylate represented byCH₂═C(R¹)COOR², which can be used in the amount mentioned above, may beselected as needed depending on the method of producing the(meth)acryl-based polymer. For example, when the (meth)acryl-basedpolymer is produced by radiation polymerization or the like, the contentof the (meth)acrylate represented by CH₂═C(R¹)COOR² is preferably morethan 0% by weight to 55% by weight, more preferably from 20 to 50% byweight, based on the total weight of all monomers, in view of adhesiveproperties. In this case, the content of the alkyl (meth)acrylate havingan alkyl group of 10 to 18 carbon atoms at the ester end is preferablyfrom 30 to 80% by weight, more preferably from 30 to 70% by weight,based on the total weight of all monomers.

Other copolymerizable monomers that may also be used include vinylmonomers such as vinyl acetate, vinyl propionate, styrene,α-methylstyrene; glycol acrylic ester monomers such as polyethyleneglycol (meth)acrylate, polypropylene glycol (meth)acrylate,methoxyethylene glycol (meth)acrylate, and methoxypolypropylene glycol(meth)acrylate; and acrylate ester monomers such as tetrahydrofurfuryl(meth)acrylate, fluoro(meth)acrylate, silicone (meth)acrylate, and2-methoxyethyl acrylate; amide group-containing monomers, aminogroup-containing monomers, imide group-containing monomers, N-acryloylmorpholine, and vinyl ether monomers. Cyclic structure-containingmonomers such as terpene (meth)acrylate and dicyclopentanyl(meth)acrylate may also be used as copolymerizable monomers.

Besides the above, a silicon atom-containing silane monomer may beexemplified as the copolymerizable monomer. Examples of the silanemonomers include 3-acryloxypropyltriethoxysilane, vinyltrimethoxysilane,vinyltriethoxysilane, 4-vinylbutyltrimethoxysilane,4-vinylbutyltriethoxysilane, 8-vinyloctyltrimethoxysilane,8-vinyloctyltriethoxysilane, 10-methacryloyloxydecyltrimethoxysilane,10-acryloyloxydecyltrimethoxysilane,10-methacryloyloxydecyltriethoxysilane, and10-acryloyloxydecyltriethoxysilane.

In the invention, if necessary, the monomer component used to form the(meth)acryl-based polymer may contain a polyfunctional monomer forcontrolling the cohesive strength of the pressure-sensitive adhesive inaddition to the monofunctional monomers listed above.

The polyfunctional monomer is a monomer having at least twopolymerizable functional groups with an unsaturated double bond such as(meth)acryloyl group or vinyl group, and examples thereof include estercompounds of a polyhydric alcohol with (meth)acrylic acid such as(poly)ethylene glycol di(meth)acrylate, (poly)propylene glycoldi(meth)acrylate, neopentyl glycol di(meth)acrylate, pentaerythritoldi(meth)acrylate, pentaerythritoltri(meth)acrylate, dipentaerythritolhexa(meth)acrylate, 1,2-ethyleneglycol di(meth)acrylate, 1,6-hexanedioldi(meth)acrylate, 1,12-dodecanediol di(meth)acrylate, trimethylolpropanetri(meth)acrylate, tetramethylolmethane tri(meth)acrylate; allyl(meth)acrylate, vinyl (meth)acrylate, divinylbenzene, epoxy acrylate,polyester acrylate, urethane acrylate, butanediol di(meth)acrylate,hexanediol di(meth)acrylate, and the like. Among them,trimethylolpropane tri(meth)acrylate, hexanediol di(meth)acrylate, anddipentaerythritol hexa (meth)acrylate can be preferably used. Thepolyfunctional monomer can be used alone or in combination of two ormore.

The content of the polyfunctional monomer, if used, is preferably 3% byweigh or less, more preferably 2% by weight or less, even morepreferably 1% by weight or less, based on the total weight of themonomer component used to form the (meth)acryl-based polymer, althoughit varies with the molecular weight of the monomer, the number of thefunctional groups, or other conditions. When the polyfunctional monomeris used in a content of more than 3% by weight, the pressure-sensitiveadhesive may have too high cohesive strength and thus have loweradhesive strength.

The (meth)acryl-based polymer described above can be produced using amethod appropriately selected from known production methods, such assolution polymerization, radiation polymerization such as UVpolymerization, bulk polymerization, and various radical polymerizationmethods including emulsion polymerization. The resultant(meth)acryl-based polymer may be any of a random copolymer, a blockcopolymer, a graft copolymer, or any other form.

Any appropriate polymerization initiator, chain transfer agent,emulsifying agent and so on may be selected and used for radicalpolymerization. The (meth)acrylic polymer may be controlled by thereaction conditions including the amount of addition of thepolymerization initiator or the chain transfer agent. The amount of theaddition may be controlled as appropriate depending on the type of thesematerials.

In a solution polymerization process and so on, for example, ethylacetate, toluene or the like is used as a polymerization solvent. In aspecific solution polymerization process, for example, the reaction isperformed under a stream of inert gas such as nitrogen at a temperatureof about 50 to about 70° C. for about 5 to about 30 hours in thepresence of a polymerization initiator.

Examples of the thermal polymerization initiator used for the solutionpolymerization process include, but are not limited to, azo initiatorssuch as 2,2′-azobisisobutyronitrile, 2,2′-azobis-2-methylbutyronitrile,2,2′-azobis(2-methylpropionic acid) dimethyl, 4,4′-azobis-4-cyanovalericacid, azobisisovaleronitrile,2,2′-azobis(2-amidinopropane)dihydrochloride,2,2′-azobis[2-(5-methyl-2-imidazoline-2-yl)propane]dihydrochlorid e,2,2′-azobis(2-methylpropionamidine)disulfate,2,2′-azobis(N,N′-dimethyleneisobutylamidine), and2,2′-azobis[N-(2-carboxyethyl)-2-methylpropionamidine]hydrate (VA-057,manufactured by Wako Pure Chemical Industries, Ltd.); persulfates suchas potassium persulfate and ammonium persulfate; peroxide initiatorssuch as di(2-ethylhexyl)peroxydicarbonate,di(4-tert-butylcyclohexyl)peroxydicarbonate,di-sec-butylperoxydicarbonate, tert-butylperoxyneodecanoate,tert-hexylperoxypivalate, tert-butylperoxypivalate, dilauroyl peroxide,di-n-octanoyl peroxide, 1,1,3,3-tetramethylbutylperoxy-2-ethylhexanoate, di(4-methylbenzoyl) peroxide, dibenzoyl peroxide,tert-butylperoxyisobutylate, 1,1-di(tert-hexylperoxy)cyclohexane,tert-butylhydroperoxide, and hydrogen peroxide; and redox systeminitiators of a combination of a peroxide and a reducing agent, such asa combination of a persulfate and sodium hydrogen sulfite and acombination of a peroxide and sodium ascorbate.

One of the above polymerization initiators may be used alone, or two ormore thereof may be used in a mixture. The content of the polymerizationinitiator is preferably from about 0.005 to 1 part by weight, even morepreferably from about 0.02 to about 0.5 parts by weight, based on 100parts by total weight of the monomer component.

For example, when 2,2′-azobisisobutyronitrile is used as apolymerization initiator for the production of the (meth)acryl-basedpolymer with the above weight average molecular weight, thepolymerization initiator is preferably used in a content of about 0.2parts by weight or less, more preferably of from about 0.06 to about 0.2parts by weight, further more preferably of from about 0.08 to about0.175 parts by weight, based on 100 parts by total weight of the monomercomponent.

Examples of the chain transfer agent include lauryl mercaptan, glycidylmercaptan, mercaptoacetic acid, 2-mercaptoethanol, thioglycolic acid,2-ethylhexyl thioglycolate and 2,3-dimercapto-1-propanol. One of thesechain transfer agents may be used alone, or two or more thereof may beused in a mixture. The total content of the chain transfer agent ispreferably about 0.1 parts by weight or less, based on 100 parts bytotal weight of the monomer component.

Examples of the emulsifier used in emulsion polymerization includeanionic emulsifiers such as sodium lauryl sulfate, ammonium laurylsulfate, sodium dodecylbenzenesulfonate, ammonium polyoxyethylene alkylether sulfate, and sodium polyoxyethylene alkyl phenyl ether sulfate;and nonionic emulsifiers such as polyoxyethylene alkyl ether,polyoxyethylene alkyl phenyl ether, polyoxyethylene fatty acid ester,and polyoxyethylene-polyoxypropylene block polymers. These emulsifiersmay be used alone, or two or more thereof may be used in combination.

The emulsifier may be a reactive emulsifier. Examples of such anemulsifier having an introduced radical-polymerizable functional groupsuch as a propenyl group and an allyl ether group include Aqualon HS-10,HS-20, KH-10, BC-05, BC-10, and BC-20 (each manufactured by Dai-ichiKogyo Seiyaku Co., Ltd.) and Adekaria Soap SE10N (manufactured by ADEKACOORPORATION). The reactive emulsifier is preferred, because afterpolymerization, it can be incorporated into a polymer chain to improvewater resistance. Based on 100 parts by total weight of the monomercomponent, the emulsifier is preferably used in a content of 0.3 to 5parts by weight, more preferably of 0.5 to 1 part by weight, in view ofpolymerization stability or mechanical stability.

The (meth)acryl-based polymer can also be produced by radiationpolymerization, in which radiation, such as electron beams or UV rays,is applied to the monomer component. When electron beams are used in theradiation polymerization, there is no particular need to add aphotopolymerization initiator to the monomer component. When UVpolymerization is used as the radiation polymerization, however, aphotopolymerization initiator may be added to the monomer component,which is advantageous particularly in that the polymerization time canbe reduced. Any of the photopolymerization initiators may be used aloneor in combination of two or more.

The photopolymerization initiator is not particularly limited as long asit can initiate photopolymerization, and photopolymerization initiatorsthat are usually used can be employed. Examples thereof that can be usedinclude benzoin ether-based photopolymerization initiator,acetophenone-based photopolymerization initiator, α-ketol-basedphotopolymerization initiator, aromatic sulfonyl chloride-basedphotopolymerization initiator, photoactive oxime-basedphotopolymerization initiator, benzoin-based photopolymerizationinitiator, benzyl-based photopolymerization initiator,benzophenone-based photopolymerization initiator, ketal-basedphotopolymerization initiator, thioxanthone-based photopolymerizationinitiator, acylphosphine oxide-based photopolymerization initiator, andthe like.

Specific examples of the benzoin ether-based photopolymerizationinitiator include benzoin methyl ether, benzoin ethyl ether, benzoinpropyl ether, benzoin isopropyl ether, benzoin isobutyl ether,2,2-dimethoxy-1,2-diphenylethan-1-one (trade name: IRGACURE 651,manufactured by BASF), anisoin methyl ether, and the like. Examples ofthe acetophenone-based photopolymerization initiator include1-hydroxycyclohexyl phenyl ketone (trade name: IRGACURE 184,manufactured by BASF), 4-phenoxydichloroacetophenone,4-t-butyl-dichloroacetophenone,1-[4-(2-hydroxyethoxy)-phenyl]-2-hydroxy-2-methyl-1-propan-1-one (tradename: IRGACURE 2959, manufactured by BASF),2-hydroxy-2-methyl-1-phenyl-propan-1-one (trade name: DAROCUR 1173,manufactured by BASF), methoxyacetophenone, and the like. Examples ofthe α-ketol-based photopolymerization initiator include2-methyl-2-hydroxypropiophenone,1-[4-(2-hydroxyethyl)-phenyl]-2-hydroxy-2-methylpropan-1-one, and thelike. Examples of the aromatic sulfonyl chloride-basedphotopolymerization initiator include 2-naphthalene sulfonyl chlorideand the like. Examples of the photoactive oxime-basedphotopolymerization initiator include1-phenyl-1,2-propanedione-2-(0-ethoxycarbonyl)-oxime, and the like.

Examples of the benzoin-based photopolymerization initiator includebenzoin and the like. Examples of the benzyl-based photopolymerizationinitiator include benzyl and the like. Examples of thebenzophenone-based photopolymerization initiators include benzophenone,benzoylbenzoic acid, 3,3′-dimethyl-4-methoxybenzophenone, polyvinylbenzophenone, α-hydroxycyclohexyl phenyl ketone, and the like. Examplesof the ketal-based photopolymerization initiator include benzyl dimethylketal and the like. Examples of the thioxanthone-basedphotopolymerization initiator include thioxanthone,2-chlorothioxanthone, 2-methylthioxanthone, 2,4-dimethylthioxanthone,isopropylthioxanthone, 2,4-dichlorothioxanthone,2,4-diethylthioxanthone, isopropylthioxanthone,2,4-diisopropylthioxanthone, dodecylthioxanthone and the like.

Examples of the acylphosphine oxide-based photopolymerization initiatorinclude bis(2,6-dimethoxybenzoyl)phenylphosphine oxide,bis(2,6-dimethoxybenzoyl)(2,4,4-trimethylpentyl)phosphine oxide,bis(2,6-dimethoxybenzoyl)-n-butylphosphine oxide,bis(2,6-dimethoxybenzoyl)-(2-methylpropan-1-yl)phosphine oxide,bis(2,6-dimethoxybenzoyl)-(1-methylpropan-1-yl)phosphine oxide,bis(2,6-dimethoxybenzoyl)-t-butylphosphine oxide,bis(2,6-dimethoxybenzoyl)cyclohexylphosphine oxide,bis(2,6-dimethoxybenzoyl)octylphosphine oxide,bis(2-methoxybenzoyl)(2-methylpropan-1-yl)phosphine oxide,bis(2-methoxybenzoyl)(1-methylpropan-1-yl)phosphine oxide,bis(2,6-diethoxybenzoyl)(2-methylpropan-1-yl)phosphine oxide,bis(2,6-diethoxybenzoyl)(1-methylpropan-1-yl)phosphine oxide,bis(2,6-dibutoxybenzoyl)(2-methylpropan-1-yl)phosphine oxide,bis(2,4-dimethoxybenzoyl)(2-methylpropan-1-yl)phosphine oxide,bis(2,4,6-trimethylbenzoyl)(2,4-dipentoxyphenyl)phosphine oxide,bis(2,6-dimethoxybenzoyl)benzylphosphine oxide,bis(2,6-dimethoxybenzoyl)-2-phenylpropylphosphine oxide,bis(2,6-dimethoxybenzoyl)-2-phenylethylphosphine oxide,bis(2,6-dimethoxybenzoyl)benzylphosphine oxide,bis(2,6-dimethoxybenzoyl)-2-phenylpropylphosphine oxide,bis(2,6-dimethoxybenzoyl)-2-phenylethylphosphine oxide,2,6-dimethoxybenzoyl benzylbutylphosphine oxide, 2,6-dimethoxybenzoylbenzyloctylphosphine oxide,bis(2,4,6-trimethylbenzoyl)-2,5-diisopropylphenylphosphine oxide,bis(2,4,6-trimethylbenzoyl)-2-methylphenylphosphine oxide,bis(2,4,6-trimethylbenzoyl)-4-methylphenylphosphine oxide,bis(2,4,6-trimethylbenzoyl)-2,5-diethylphenylphosphine oxide,bis(2,4,6-trimethylbenzoyl)-2,3,5,6-tetramethylphenylphosphine oxide,bis(2,4,6-trimethylbenzoyl)-2,4-di-n-butoxyphenylphosphine oxide,2,4,6-trimethylbenzoyl diphenylphosphine oxide,bis(2,6-dimethoxybenzoyl)-2,4,4-trimethylpentylphosphine oxide,bis(2,4,6-trimethylbenzoyl)isobutylphosphine oxide, 2,6-dimethoxybenzoyl-2, 4, 6-trimethylbenzoyl-n-butylphosphine oxide,bis(2,4,6-trimethylbenzoyl)phenylphosphine oxide,bis(2,4,6-trimethylbenzoyl)-2,4-dibutoxyphenylphosphine oxide,1,10-bis[bis(2,4,6-trimethylbenzoyl)phosphine oxide]decane,tri(2-methylbenzoyl)phosphine oxide, and the like.

The content of the photopolymerization initiator is not particularlylimited, but is preferably 0.01 to 5 parts by weight, more preferably0.05 to 3 parts by weight, furthermore preferably 0.05 to 1.5 parts byweight, and particularly preferably 0.1 to 1 part by weight, based on100 parts by total weight of the monomer component.

If the photopolymerization initiator is used in an amount of less than0.01 parts by weight, the polymerization reaction may be insufficient.If the photopolymerization initiator is used in an amount of more than 5parts by weight, the photopolymerization initiator may absorbultraviolet rays, so that ultraviolet rays may fail to reach the insideof the pressure-sensitive adhesive layer. In this case, the degree ofpolymerization may decrease, or a polymer with a lower molecular weightmay be produced. This may cause the resulting pressure-sensitiveadhesive layer to have lower cohesive strength, so that in the processof peeling off the pressure-sensitive adhesive layer from a film, thepressure-sensitive adhesive layer may partially remain on the film,which may make it impossible to reuse the film. The photopolymerizationinitiators may be used singly or in combination of two or more.

In the invention, the (meth)acryl-based polymer preferably has a weightaverage molecular weight of 400,000 to 2,500,000, more preferably600,000 to 2,200,000. When the weight average molecular weight is morethan 400,000, the pressure-sensitive adhesive layer can havesatisfactory durability and can have a cohesive strength small enough tosuppress adhesive residue. On the other hand, if the weight averagemolecular weight is more than 2,500,000, bonding ability or adhesivestrength may tend to be lower. In this case, the pressure-sensitiveadhesive may form a solution with too high a viscosity, which may bedifficult to apply. As used herein, the term “weight average molecularweight” refers to a polystyrene-equivalent weight average molecularweight, which is determined using gel permeation chromatography (GPC).It should be noted that the molecular weight of the (meth)acryl-basedpolymer obtained by radiation polymerization would be difficult tomeasure.

<Measurement of Weight Average Molecular Weight>

The weight average molecular weight of the obtained (meth)acryl-basedpolymer was measured by gel permeation chromatography (GPC) as follows.The polymer sample was dissolved in tetrahydrofuran to form a 0.1% byweight solution. After allowed to stand overnight, the solution wasfiltered through a 0.45 μm membrane filter, and the filtrate was usedfor the measurement.

Analyzer: HLC-8120GPC manufactured by TOSOH CORPORATIONColumns: (meth)acryl-based polymer, GM7000H_(XL)+GMH_(XL)+GMH_(XL),manufactured by TOSOH CORPORATION, aromatic-based polymer,G3000HXL+2000HXL+G1000HXL, manufactured by TOSOH CORPORATIONColumn size: each 7.8 mmφ×30 cm, 90 cm in totalEluent: tetrahydrofuran (concentration 0.1% by weight)Flow rate: 0.8 ml/minuteInlet pressure: 1.6 MPaDetector: differential refractometer (RI)Column temperature: 40° C.Injection volume: 100 μlStandard sample: polystyrene

The pressure-sensitive adhesive of the invention may contain acrosslinking agent. Examples of the crosslinking agents include anisocyanate crosslinking agent, an epoxy crosslinking agent, a siliconecrosslinking agent, an oxazoline crosslinking agent, an aziridinecrosslinking agent, a silane crosslinking agent, an alkyl etherifiedmelamine crosslinking agent, a metallic chelate crosslinking agent and aperoxide. Such crosslinking agents may be used alone or in combinationof two or more. An isocyanate crosslinking agent or an epoxycrosslinking agent is preferably used as the crosslinking agent.

These crosslinking agents may be used alone or in a mixture of two ormore. The total content of the crosslinking agent(s) is preferably 5parts by weight or less, more preferably 0.01 to 5 parts by weight, evenmore preferably 0.01 to 4 parts by weight, still more preferably 0.02 to3 parts by weight, based on 100 parts by weight of the (meth)acryl-basedpolymer.

The term “isocyanate crosslinking agent” refers to a compound having twoor more isocyanate groups (which may include functional groups that aretemporarily protected with an isocyanate blocking agent or byoligomerization and are convertible to isocyanate groups) per molecule.

Isocyanate crosslinking agents include aromatic isocyanates such astolylene diisocyanate and xylene diisocyanate, alicyclic isocyanatessuch as isophorone diisocyanate, and aliphatic isocyanates such ashexamethylene diisocyanate.

More specifically, examples of isocyanate crosslinking agents includelower aliphatic polyisocyanates such as butylene diisocyanate andhexamethylene diisocyanate; alicyclic isocyanates such as cyclopentylenediisocyanate, cyclohexylene diisocyanate, and isophorone diisocyanate;aromatic diisocyanates such as 2, 4-tolylene diisocyanate,4,4′-diphenylmethane diisocyanate, xylylene diisocyanate, andpolymethylene polyphenyl isocyanate; isocyanate adducts such as atrimethylolpropane-tolylene diisocyanate trimer adduct (trade name:CORONATE L, manufactured by NIPPON POLYURETHANE INDUSTRY CO., LTD.), atrimethylolpropane-hexamethylene diisocyanate trimer adduct (trade name:CORONATE HL, manufactured by NIPPON POLYURETHANE INDUSTRY CO., LTD.),and an isocyanurate of hexamethylene diisocyanate (trade name: CORONATEHX, manufactured by NIPPON POLYURETHANE INDUSTRY CO., LTD.); atrimethylolpropane adduct of xylylene diisocyanate (trade name: D110N,manufactured by Mitsui Chemicals, Inc.) and a trimethylolpropane adductof hexamethylene diisocyanate (trade name: D160N, manufactured by MitsuiChemicals, Inc.); polyether polyisocyanate and polyester polyisocyanate;adducts thereof with various polyols; and polyisocyanatespolyfunctionalized with an isocyanurate bond, a biuret bond, anallophanate bond, or the like. In particular, aliphatic isocyanates arepreferably used because of their high reaction speed.

These isocyanate crosslinking agents may be used alone or in a mixtureof two or more. The total content of the isocyanate crosslinkingagent(s) is preferably 0.01 to 5 parts by weight, more preferably 0.01to 4 parts by weight, further more preferably 0.02 to 3 parts by weight,based on 100 parts by weight of the (meth)acryl-based polymer. Thecontent may be appropriately determined taking into account cohesivestrength, the ability to prevent delamination in a durability test, orother properties.

When an aqueous dispersion of a modified (meth)acryl-based polymerproduced by emulsion polymerization is used, the isocyanate crosslinkingagent does not have to be used. If necessary, however, a blockedisocyanate crosslinking agent may also be used in such a case, becausethe isocyanate crosslinking agent itself can easily react with water.

The term “epoxy crosslinking agent” refers to a polyfunctional epoxycompound having two or more epoxy groups per molecule. Examples of theepoxy crosslinking agent include bisphenol A, epichlorohydrin-type epoxyresin, ethylene glycol diglycidyl ether,N,N,N′,N′-tetraglycidyl-m-xylenediamine, diglycidylaniline, N,N-diaminoglycidyl amine, 1,3-bis(N,N-diglycidylaminomethyl)cyclohexane,1,6-hexanediol diglycidyl ether, neopentyl glycol diglycidyl ether,ethylene glycol diglycidyl ether, propylene glycol diglycidyl ether,polyethylene glycol diglycidyl ether, polypropylene glycol diglycidylether, sorbitol polyglycidyl ether, glycerol polyglycidyl ether,pentaerythritol polyglycidyl ether, glycerine diglycidyl ether,glycerine triglycidyl ether, polyglycerol polyglycidyl ether, sorbitanpolyglycidyl ether, trimethylolpropane polyglycidyl ether, diglycidyladipate, diglycidyl o-phthalate, triglycidyltris(2-hydroxyethyl)isocyanurate, resorcin diglycidyl ether, bisphenol-Sdiglycidyl ether, and epoxy resins having two or more epoxy groups inthe molecule. The epoxy crosslinking agent may also be a commerciallyavailable product such as TETRAD-C (trade name) or TETRAD-X (trade name)manufactured by MITSUBISHI GAS CHEMICAL COMPANY, INC.

These epoxy crosslinking agents may be used alone or in a mixture of twoor more. The total content of the epoxy crosslinking agent(s) ispreferably 0.01 to 5 parts by weight, more preferably 0.01 to 4 parts byweight, further more preferably 0.02 to 3 parts by weight, based on 100parts by weight of the (meth)acryl-based polymer. The content may beappropriately determined taking into account cohesive strength, theability to prevent delamination in a durability test, or otherproperties.

Any peroxide crosslinking agents capable of generating active radicalspecies by heating and promoting the crosslinking of the base polymer inthe pressure-sensitive adhesive may be appropriately used. In view ofworkability and stability, a peroxide with a one-minute half-lifetemperature of 80° C. to 160° C. is preferably used, and a peroxide witha one-minute half-life temperature of 90° C. to 140° C. is morepreferably used.

Examples of the peroxide for use in the invention includedi(2-ethylhexyl) peroxydicarbonate (one-minute half-life temperature:90.6° C.), di(4-tert-butylcyclohexyl) peroxydicarbonate (one-minutehalf-life temperature: 92.1° C.), di-sec-butyl peroxydicarbonate(one-minute half-life temperature: 92.4° C.), tert-butylperoxyneodecanoate (one-minute half-life temperature: 103.5° C.),tert-hexyl peroxypivalate (one-minute half-life temperature: 109.1° C.),tert-butyl peroxypivalate (one-minute half-life temperature: 110.3° C.),dilauroyl peroxide (one-minute half-life temperature: 116.4° C.),di-n-octanoylperoxide (one-minute half-life temperature: 117.4° C.),1,1,3,3-tetramethylbutylperoxy-2-ethyl hexanoate (one-minute half-lifetemperature: 124.3° C.), di(4-methylbenzoyl) peroxide (one-minutehalf-life temperature: 128.2° C.), dibenzoyl peroxide (one-minutehalf-life temperature: 130.0° C.), tert-butyl peroxyisobutylate(one-minute half-life temperature: 136.1° C.), and1,1-di(tert-hexylperoxy)cyclohexane (one-minute half-life temperature:149.2° C.). In particular, di(4-tert-butylcyclohexyl) peroxydicarbonate(one-minute half-life temperature: 92.1° C.), dilauroyl peroxide(one-minute half-life temperature: 116.4° C.), dibenzoyl peroxide(one-minute half-life temperature: 130.0° C.), or the like is preferablyused, because they can provide high crosslinking reaction efficiency.

The half life of the peroxide is an indicator of how fast the peroxidecan be decomposed and refers to the time required for the amount of theperoxide to reach one half of its original value. The decompositiontemperature required for a certain half life and the half life timeobtained at a certain temperature are shown in catalogs furnished bymanufacturers, such as “Organic Peroxide Catalog, 9th Edition, May,2003” furnished by NOF CORPORATION.

One of the peroxide crosslinking agents may be used alone, or a mixtureof two or more of the peroxide crosslinking agent may be used. The totalcontent of the peroxide(s) is preferably from 0.02 to 2 parts by weight,more preferably from 0.05 to 1 part by weight, based on 100 parts byweight of the (meth)acrylic polymer. The content of the peroxide (s) maybe appropriately selected in this range in order to control theworkability, reworkability, crosslink stability or peeling properties.

The amount of decomposition of the peroxide may be determined bymeasuring the peroxide residue after the reaction process by highperformance liquid chromatography (HPLC).

More specifically, for example, after the reaction process, about 0.2 gof each pressure-sensitive adhesive composition is taken out, immersedin 10 ml of ethyl acetate, subjected to shaking extraction at 25° C. and120 rpm for 3 hours in a shaker, and then allowed to stand at roomtemperature for 3 days. Thereafter, 10 ml of acetonitrile is added, andthe mixture is shaken at 25° C. and 120 rpm for 30 minutes. About 10 μlof the liquid extract obtained by filtration through a membrane filter(0.45 μm) is subjected to HPLC by injection and analyzed so that theamount of the peroxide after the reaction process is determined.

As the crosslinking agent, a polyfunctional metal chelate may also beused in combination with an organic crosslinking agent. Examples of thepolyfunctional metal chelate may include a polyvalent metal and anorganic compound that is covalently or coordinately bonded to the metal.Examples of the polyvalent metal atom include Al, Cr, Zr, Co, Cu, Fe,Ni, V, Zn, In, Ca, Mg, Mn, Y, Ce, Sr, Ba, Mo, La, Sn, and Ti. Theorganic compound has a covalent or coordinate bond-forming atom such asan oxygen atom. Examples of the organic compound include alkyl esters,alcohol compounds, carboxylic acid compounds, ether compounds, andketone compounds.

The pressure-sensitive adhesive of the invention may contain a(meth)acryl-based oligomer in view of improving adhesive strength. The(meth)acryl-based oligomer is preferably a polymer having a Tg higherthan that of the (meth)acryl-based polymer according to the inventionand having a weight average molecular weight lower than that of the(meth)acryl-based polymer according to the invention. The(meth)acryl-based oligomer functions as a tackifying resin and isadvantageous in increasing adhesive strength without raising dielectricconstant.

The (meth)acryl-based oligomer may have a Tg of from about 0° C. toabout 300° C., preferably from about 20° C. to about 300° C., morepreferably from about 40° C. to about 300° C. When the Tg falls withinthe range, the adhesive strength can be improved. Like the Tg of the(meth)acryl-based polymer, the Tg of the (meth)acryl-based oligomer isthe theoretical value calculated from the Fox equation.

The (meth)acryl-based oligomer may have a weight average molecularweight of 1,000 to less than 30,000, preferably 1,500 to less than20,000, more preferably 2,000 to less than 10,000. If the oligomer has aweight average molecular weight of 30,000 or more, the effect ofimproving adhesive strength cannot be sufficiently obtained in somecases. The oligomer with a weight average molecular weight of less than1,000 may lower the adhesive strength or holding performance because ofits relatively low molecular weight. In the invention, the weightaverage molecular weight of the (meth)acryl-based oligomer can bedetermined as a polystyrene-equivalent weight average molecular weightby GPC method. More specifically, the weight average molecular weightcan be determined using HPLC 8020 with two TSKgel GMH-H (20) columnsmanufactured by TOSOH CORPORATION under the conditions of a solvent oftetrahydrofuran and a flow rate of about 0.5 ml/minute.

Examples of monomers that may be used to form the (meth)acryl-basedoligomer include alkyl (meth)acrylate such as methyl (meth)acrylate,ethyl (meth)acrylate, propyl (meth)acrylate, isopropyl (meth)acrylate,butyl (meth)acrylate, isobutyl (meth)acrylate, sec-butyl (meth)acrylate,tert-butyl (meth)acrylate, pentyl (meth)acrylate, isopentyl(meth)acrylate, hexyl (meth)acrylate, 2-ethylhexyl (meth)acrylate,heptyl (meth)acrylate, octyl (meth)acrylate, isooctyl (meth)acrylate,nonyl (meth)acrylate, isononyl (meth)acrylate, decyl (meth)acrylate,isodecyl (meth)acrylate, undecyl (meth)acrylate, or dodecyl(meth)acrylate; an ester of (meth)acrylic acid and an alicyclic alcohol,such as cyclohexyl (meth)acrylate or isobornyl (meth)acrylate; aryl(meth)acrylate such as phenyl (meth)acrylate or benzyl (meth)acrylate;and a (meth)acrylate derived from a terpene compound derivative alcohol.These (meth)acrylates may be used alone or in combination of two ormore.

The (meth)acryl-based oligomer preferably contains, as a monomer unit,an acrylic monomer having a relatively bulky structure, typified by analkyl (meth)acrylate whose alkyl group has a branched structure, such asisobutyl (meth)acrylate or tert-butyl (meth)acrylate; an ester of(meth)acrylic acid and an alicyclic alcohol, such as cyclohexyl(meth)acrylate or isobornyl (meth)acrylate; or aryl (meth)acrylate suchas phenyl (meth)acrylate or benzyl (meth)acrylate, or any other cyclicstructure-containing (meth)acrylate. The use of a (meth)acryl-basedoligomer with such a bulky structure can further improve the tackinessof the pressure-sensitive adhesive layer. In terms of bulkiness, cyclicstructure-containing oligomers are highly effective, and oligomershaving two or more rings are more effective. When ultraviolet (UV) lightis used in the process of synthesizing the (meth)acryl-based oligomer orforming the pressure-sensitive adhesive layer, a saturated oligomer ispreferred because such an oligomer is less likely to inhibitpolymerization, and an alkyl (meth)acrylate whose alkyl group has abranched structure or an ester of an alicyclic alcohol and (meth)acrylicacid is preferably used as a monomer to form the (meth)acryl-basedoligomer.

From these points of view, preferred examples of the (meth)acryl-basedoligomer include a copolymer of cyclohexyl methacrylate (CHMA) andisobutyl methacrylate (IBMA), a copolymer of cyclohexyl methacrylate(CHMA) and isobornyl methacrylate (IBXMA), a copolymer of cyclohexylmethacrylate (CHMA) and acryloyl morpholine (ACMO), a copolymer ofcyclohexyl methacrylate (CHMA) and diethylacrylamide (DEAA), a copolymerof 1-adamanthyl acrylate (ADA) and methyl methacrylate (MMA), acopolymer of dicyclopentanyl methacrylate (DCPMA) and isobornylmethacrylate (IBXMA), and a homopolymer of each of dicyclopentanylmethacrylate (DCPMA), cyclohexyl methacrylate (CHMA), isobornylmethacrylate (IBXMA), isobornyl acrylate (IBXA), a copolymer ofdicyclopentanyl methacrylate (DCPMA) and methyl methacrylate (MMA),dicyclopentanyl acrylate (DCPA), 1-adamanthyl methacrylate (ADMA), and1-adamanthyl acrylate (ADA). In particular, an oligomer composed mainlyof CHMA is preferred.

In the pressure-sensitive adhesive of the invention, the content of the(meth)acryl-based oligomer is preferably, but not limited to, 70 partsby weight or less, more preferably from 1 to 70 parts by weight, evenmore preferably from 2 to 50 parts by weight, still more preferably from3 to 40 parts by weight, based on 100 parts by weight of the(meth)acryl-based polymer. If the content of the (meth)acryl-basedoligomer is more than 70 parts by weight, a problem may occur such as anincrease in elastic modulus or a decrease in tackiness at lowtemperature. Adding 1 part by weight or more of the (meth)acryl-basedoligomer is effective in improving adhesive strength.

The pressure-sensitive adhesive of the invention may further contain asilane coupling agent for improving water resistance at the interfacebetween the pressure-sensitive adhesive layer and a hydrophilicadherend, such as glass, bonded thereto. The content of the silanecoupling agent is preferably 1 part by weight or less, more preferablyfrom 0.01 to 1 part by weight, even more preferably from 0.02 to 0.6parts by weight, based on 100 parts by weight of the (meth)acryl-basedpolymer. If the content of the silane coupling agent is too high, theadhesive may have a higher adhesive strength to glass so that it may beless removable from glass. If the content of the silane coupling agentis too low, the durability of the adhesive may undesirably decrease.

Examples of silane coupling agent preferably can be used include epoxygroup-containing silane coupling agents such as3-glycidoxypropyltrimethoxysilane, 3-glycidoxypropyltriethoxysilane,3-glycidoxypropylmethyldiethoxysilane, and2-(3,4-epoxycyclohexyl)ethyltrimethoxysilane; amino group-containingsilane coupling agents such as 3-aminopropyltrimethoxysilane,N-(2-aminoethyl)-3-aminopropylmethyldimethoxysilane,3-triethoxysilyl-N-(1,3-dimethylbutylidene)propylamine andN-phenyl-γ-aminopropyltrimethoxysilane; (meth)acrylic group-containingsilane coupling agents such as 3-acryloxypropyltrimethoxysilane and3-methacryloxypropyltriethoxysilane; and isocyanate group-containingsilane coupling agents such as 3-isocyanatepropyltriethoxysilane.

The pressure-sensitive adhesive composition of the invention may alsocontain any other known additive. For example, a powder such as acolorant and a pigment, a dye, a surfactant, a plasticizer, a tackifier,a surface lubricant, a leveling agent, a softening agent, anantioxidant, an age resister, a light stabilizer, an ultravioletabsorbing agent, a polymerization inhibitor, an inorganic or organicfiller, a metal powder, or a particle- or foil-shaped material may beadded as appropriate depending on the intended use.

The pressure-sensitive adhesive layer of the invention is made from thepressure-sensitive adhesive described above. The thickness of thepressure-sensitive adhesive layer is typically, but not limited to,about 1 to about 400 μm. The preferred range of the thickness of thepressure-sensitive adhesive layer may be appropriately determineddepending on the method of producing the (meth)acryl-based polymer usedto form the pressure-sensitive adhesive. For example, when the(meth)acryl-based polymer is produced by solution polymerization or thelike, the thickness of the pressure-sensitive adhesive layer ispreferably from 1 to 100 μm, more preferably from 2 to 50 μm, even morepreferably from 2 to 40 μm, still more preferably from 5 to 35 μm. Whenthe (meth)acryl-based polymer is produced by radiation polymerization orthe like, the thickness of the pressure-sensitive adhesive layer ispreferably from 50 to 400 μm, more preferably from 75 to 300 μm, evenmore preferably from 100 to 200 μm.

The pressure-sensitive adhesive layer of the invention preferably has arelative dielectric constant of 3.5 or less, more preferably 3.3 orless, even more preferably 3.2 or less, still more preferably 3.0 orless at a frequency of 100 kHz.

The pressure-sensitive adhesive layer of the invention preferably has agel fraction of 20 to 98% by weight. The gel fraction of thepressure-sensitive adhesive layer is more preferably from 30 to 98% byweight, even more preferably from 40 to 95% by weight. When thepressure-sensitive adhesive contains a crosslinking agent, the gelfraction can be controlled by adjusting the total amount of thecrosslinking agent (s) added, taking carefully into account the effectof the crosslinking treatment temperature and the crosslinking treatmenttime. As the gel fraction decreases, the cohesive strength may decrease.As the gel fraction excessively increases, the adhesive strength maydegrade. The pressure-sensitive adhesive layer having a gel fraction insuch a range is characterized in that it shows only a very smallincrease in adhesive strength after bonded to an adherend and that itcan be easily removed from the adherend without leaving adhesive residueeven after bonded thereto for a long period of time.

The pressure-sensitive adhesive layer of the invention preferably has ahaze value of 2% or less when having a thickness of 25 μm. Thepressure-sensitive adhesive layer with a haze value of 2% or less cansatisfy the requirements for transparency when it is used on opticalmembers. The haze value is preferably from 0 to 1.5%, more preferablyfrom 0 to 1%. A haze value of 2% or less is a satisfactory level foroptical applications. If the haze value is more than 2%, cloudiness mayoccur, which is not preferred for optical film applications.

The transparency of the pressure-sensitive adhesive layer is consideredto depend on the total content of the hydroxyl group-containing monomerand the cyclic nitrogen-containing monomer based on the total amount ofthe monomer component. If the total content is high, the transparencycan be high, but too high a total content may have an adverse effect onother properties. Therefore, for example, when the content of the cyclicnitrogen-containing monomer is low, the transparency can be controlledusing the hydroxyl group-containing monomer.

For example, the pressure-sensitive adhesive layer may be formed by amethod including applying the pressure-sensitive adhesive to a support,removing the polymerization solvent and so on by drying to form apressure-sensitive adhesive sheet. Before the pressure-sensitiveadhesive is applied, appropriately at least one solvent other than thepolymerization solvent may be added to the pressure-sensitive adhesive.

Various methods may be used to apply the pressure-sensitive adhesivelayer. Specific examples of such methods include roll coating, kiss rollcoating, gravure coating, reverse coating, roll brush coating, spraycoating, dip roll coating, bar coating, knife coating, air knifecoating, curtain coating, lip coating, and extrusion coating with a diecoater or the like.

The heat drying temperature is preferably from 40° C. to 200° C., morepreferably from 50° C. to 180° C., in particular, preferably from 70° C.to 170° C. Setting the heating temperature within the above range makesit possible to obtain a pressure-sensitive adhesive layer having goodadhesive properties. The drying time may be any appropriate period oftime. The drying time is preferably from 5 seconds to 20 minutes, morepreferably from 5 seconds to 10 minutes, in particular, preferably from10 seconds to 5 minutes.

When the (meth)acryl-based polymer according to the invention isproduced by ultraviolet irradiation of the monomer component to bepolymerized, the pressure-sensitive adhesive layer may be formed whilethe (meth)acryl-based polymer is produced from the monomer component.Appropriate materials such as a crosslinking agent and other materialsthat may be added to the pressure-sensitive adhesive may also be mixedwith the monomer component. Before the ultraviolet irradiation, themonomer component may be partially polymerized to form a syrup beforeuse. The ultraviolet irradiation may be performed using a high-pressuremercury lamp, a low-pressure mercury lamp, a metal halide lamp, or thelike.

For example, a release-treated sheet may be used as the support. Asilicone release liner is preferably used as the release-treated sheet.

In the pressure-sensitive adhesive sheet include the layerpressure-sensitive adhesive layer formed on the release-treated sheet,when the pressure-sensitive adhesive layer is exposed, thepressure-sensitive adhesive layer may be protected with therelease-treated sheet (a separator) before practical use. Therelease-treated sheet is peeled off before actual use.

Examples of the material for forming the separator include a plasticfilm such as a polyethylene, polypropylene, polyethylene terephthalate,or polyester film, a porous material such as paper, cloth and nonwovenfabric, and an appropriate thin material such as a net, a foamed sheet,a metal foil, and a laminate thereof. In particular, a plastic film ispreferably used, because of its good surface smoothness.

The plastic film may be any film capable of protecting thepressure-sensitive adhesive layer, and examples thereof include apolyethylene film, a polypropylene film, a polybutene film, apolybutadiene film, a polymethylpentene film, a polyvinyl chloride film,a vinyl chloride copolymer film, a polyethylene terephthalate film, apolybutylene terephthalate film, a polyurethane film, and anethylene-vinyl acetate copolymer film.

The thickness of the separator is generally from about 5 to about 200μm, preferably from about 5 to about 100 μm. If necessary, the separatormay be treated with a release agent such as a silicone, fluorine,long-chain alkyl, or fatty acid amide release agent, or may be subjectedto release and antifouling treatment with silica powder or to antistatictreatment of coating type, kneading and mixing type, vapor-depositiontype, or the like. In particular, if the surface of the separator isappropriately subjected to release treatment such as silicone treatment,long-chain alkyl treatment, and fluorine treatment, the releasabilityfrom the pressure-sensitive adhesive layer can be further increased.

The pressure-sensitive adhesive layer and the pressure-sensitiveadhesive sheet of the invention are suitable for use on optical members,and particularly in optical applications, they are preferably used andbonded to metal thin layers or metal electrodes. Metal thin layersinclude thin layers of metal, metal oxide, or a mixture of metal andmetal oxide, and examples of metal thin layers include, but are notlimited to, thin layers of ITO (indium tin oxide), ZnO, SnO, and CTO(cadmium tin oxide). The thickness of metal thin layers is typically,but not limited to, about 10 to 200 nm. Usually, for example, a metalthin layer such as an ITO layer is provided on a transparent plasticfilm substrate such as a polyethylene terephthalate film (specifically,a PET film) to form a transparent conductive film for use. When thepressure-sensitive adhesive sheet of the invention is bonded to a metalthin layer, the surface of the pressure-sensitive adhesive layer ispreferably used as a bonding surface to the metal thin layer.

The metal electrodes may be made of metal, metal oxide, or a mixture ofmetal and metal oxide, and examples include, but are not limited to,ITO, silver, copper, and carbon nanotube (CNT) electrodes.

A specific example of the use of the pressure-sensitive adhesive sheetof the invention is a touch panel-forming pressure-sensitive adhesivesheet, which is used in the manufacture of a touch panel. For example,the touch panel-forming pressure-sensitive adhesive sheet is used in themanufacture of a capacitance touch panel, where it is used to bond atransparent conductive film having a metal thin layer such as an ITOlayer to a poly (methyl methacrylate) (PMMA) resin sheet, a hard-coatedfilm, a glass lens, or any other material. Applications of the touchpanel include, but are not limited to, cellular phones, tabletcomputers, and personal digital assistances.

FIG. 1 shows a more specific example of the use of thepressure-sensitive adhesive layer or the pressure-sensitive adhesivesheet of the invention, which is an example of a capacitance touchpanel. FIG. 1 shows a capacitance touch panel 1 including a decorativepanel 11, pressure-sensitive adhesive layers or pressure-sensitiveadhesive sheets 12, ITO films 13, and a hard coated film 14. Thedecorative panel 11 is preferably a glass plate or a transparent acrylicplate (PMMA plate). Each ITO films 13 preferably includes a glass sheetor a transparent plastic film (specifically, a PET film) and an ITOlayer provided thereon. The hard coated film 14 is preferably a hardcoated transparent plastic film such as a hard coated PET film. Thecapacitance touch panel 1 having the pressure-sensitive adhesive layeror the pressure-sensitive adhesive sheet of the invention can be madethinner and more stable in operation. The capacitance touch panel 1 alsohas a good appearance and good visibility.

An optical member may be used as the support of the pressure-sensitiveadhesive sheet of the invention. The pressure-sensitive adhesive layercan be formed by a process including applying the pressure-sensitiveadhesive directly to an optical member and drying the adhesive to removethe polymerization solvent and the like, so that the pressure-sensitiveadhesive layer is formed on the optical member. Alternatively, thepressure-sensitive adhesive layer may be formed on a release-treatedseparator and then transferred to an optical member as needed to form apressure-sensitive adhesive optical member.

The release-treated sheet used in the preparation of thepressure-sensitive adhesive optical member may be used by itself as aseparator for the pressure-sensitive adhesive optical member, so thatthe process can be simplified.

The process for forming the pressure-sensitive adhesive layer for thepressure-sensitive adhesive optical member may further include formingan anchor layer on the surface of the optical member or performing anyadhesion-facilitating treatment such as a corona treatment or a plasmatreatment before forming the pressure-sensitive adhesive layer. Thesurface of the pressure-sensitive adhesive layer may also be subjectedto an adhesion-facilitating treatment.

The pressure-sensitive adhesive optical member of the invention may beused as a pressure-sensitive adhesive layer-carrying transparentconductive film, which is produced using a transparent conductive filmas an optical member. The transparent conductive film includes atransparent plastic film substrate and a transparent conductive thinlayer that is formed of a metal thin layer such as the ITO layer on onesurface of the substrate. The pressure-sensitive adhesive layer of theinvention is provided on the other surface of the transparent plasticfilm substrate. The transparent conductive thin layer may be provided onthe transparent plastic film substrate with an undercoat layerinterposed therebetween. Two or more undercoat layers may be provided.An oligomer migration-preventing layer may be provided between thetransparent plastic film substrate and the pressure-sensitive adhesivelayer.

The transparent plastic film substrate to be used may be, but notlimited to, various transparent plastic films. The plastic film isgenerally formed of a monolayer film. Examples of the material for thetransparent plastic film substrate include polyester resins such aspolyethylene terephthalate and polyethylene naphthalate, acetate resins,polyethersulfone resins, polycarbonate resins, polyamide resins,polyimide resins, polyolefin resins, (meth)acrylic resins, polyvinylchloride resins, polyvinylidene chloride resins, polystyrene resins,polyvinyl alcohol resins, polyarylate resins, and polyphenylene sulfideresins. In particular, polyester resins, polyimide resins, andpolyethersulfone resins are preferred. The film substrate preferably hasa thickness of 15 to 200 μm.

The surface of the film substrate may be previously subject tosputtering, corona discharge treatment, flame treatment, ultravioletirradiation, electron beam irradiation, chemical treatment, etchingtreatment such as oxidation, or undercoating treatment such that theadhesion of the transparent conductive thin layer or the undercoat layerformed thereon to the transparent plastic film substrate can beimproved. If necessary, the film substrate may also be subjected to dustremoving or cleaning by solvent cleaning, ultrasonic cleaning or thelike, before the transparent conductive thin layer or the undercoatlayer is formed.

The material and thickness of the transparent conductive thin layer arenot restricted and may be those described for the metal thin layer. Theundercoat layer may be made of an inorganic material, an organicmaterial or a mixture of an inorganic material and an organic material.Examples of the inorganic material include NaF (1.3), Na₃AlF₆ (1.35),LiF (1.36), MgF₂ (1.38), CaF₂ (1.4), BaF₂ (1.3), SiO₂ (1.46), LaF₃(1.55), CeF₃ (1.63), and Al₂O₃ (1.63), wherein each number inside theparentheses is the refractive index of each material. In particular,SiO₂, MgF₂, Al₂O₃, or the like is preferably used. In particular, SiO₂is preferred. Besides the above, a complex oxide containing about 10 toabout 40 parts by weight of cerium oxide and about 0 to about 20 partsby weight of tin oxide based on 100 parts by weight of the indium oxidemay also be used.

Examples of the organic material include acrylic resins, urethaneresins, melamine resins, alkyd resins, siloxane polymers, andorganosilane-based condensates. At least one of these organic materialsmay be used. In particular, a thermosetting resin including a mixturecomposed of a melamine resin, an alkyd resin and an organosilanecondensate is preferably used as the organic material.

The thickness of the undercoat layer is generally, but not limited to,from about 1 to about 300 nm, preferably from 5 to 300 nm, in view ofoptical design and the effect of preventing the release of an oligomerfrom the film substrate.

The pressure-sensitive adhesive layer-carrying transparent conductivefilm can be used to form various devices such as touch panels and liquidcrystal display devices. In particular, the pressure-sensitive adhesivelayer-carrying transparent conductive film is preferably used as a touchpanel-forming electrode sheet. The touch panel is suitable for use indifferent types of detection (such as resistive and capacitance types).

A capacitance touch panel usually includes a transparent conductive filmthat has a transparent conductive thin layer in a specific pattern andis formed over the surface of a display unit. The pressure-sensitiveadhesive layer-carrying transparent conductive film is a laminate inwhich the pressure-sensitive adhesive layer and the patternedtransparent conductive thin layer are appropriately stacked facing eachother.

The pressure-sensitive adhesive optical member of the invention may beused as a pressure-sensitive adhesive layer-carrying optical film, whichis produced using an image display-forming optical film as the opticalmember.

The optical film may be of any type for use in forming image displaydevices such as liquid crystal display devices and organicelectro-luminescent (EL) display devices. For example, a polarizingplate is exemplified as the optical film. A polarizing plate including apolarizer and a transparent protective film provided on one or bothsides of the polarizer is generally used.

A polarizer is not limited especially but various kinds of polarizer maybe used. As a polarizer, for example, a film that is uniaxiallystretched after having dichromatic substances, such as iodine anddichromatic dye, absorbed to hydrophilic high molecular weight polymerfilms, such as polyvinyl alcohol type film, partially formalizedpolyvinyl alcohol type film, and ethylene-vinyl acetate copolymer typepartially saponified film; poly-ene type alignment films, such asdehydrated polyvinyl alcohol and dehydrochlorinated polyvinyl chloride,etc. may be mentioned. In these, a polyvinyl alcohol type film on whichdichromatic materials such as iodine, is absorbed and aligned afterstretched is suitably used. Although thickness of polarizer is notespecially limited, the thickness of about 5 to 80 μm is commonlyadopted.

A polarizer that is uniaxially stretched after a polyvinyl alcohol typefilm dyed with iodine is obtained by stretching a polyvinyl alcohol filmby 3 to 7 times the original length, after dipped and dyed in aqueoussolution of iodine. If needed the film may also be dipped in aqueoussolutions, such as boric acid and potassium iodide, which may includezinc sulfate, zinc chloride. Furthermore, before dyeing, the polyvinylalcohol type film may be dipped in water and rinsed if needed. Byrinsing polyvinyl alcohol type film with water, effect of preventingun-uniformity, such as unevenness of dyeing, is expected by makingpolyvinyl alcohol type film swelled in addition that also soils andblocking inhibitors on the polyvinyl alcohol type film surface may bewashed off. Stretching may be applied after dyed with iodine or may beapplied concurrently, or conversely dyeing with iodine may be appliedafter stretching. Stretching is applicable in aqueous solutions, such asboric acid and potassium iodide, and in water bath.

A thermoplastic resin with a high level of transparency, mechanicalstrength, thermal stability, moisture blocking properties, isotropy, andthe like may be used as a material for forming the transparentprotective film. Examples of such a thermoplastic resin includecellulose resins such as triacetylcellulose, polyester resins,polyethersulfone resins, polysulfone resins, polycarbonate resins,polyamide resins, polyimide resins, polyolefin resins, (meth)acrylicresins, cyclic olefin polymer resins (norbornene resins), polyarylateresins, polystyrene resins, polyvinyl alcohol resins, and any mixturethereof. The transparent protective film is generally laminated to oneside of the polarizer with the adhesive layer, but thermosetting resinsor ultraviolet curing resins such as (meth)acrylic, urethane, acrylicurethane, epoxy, or silicone resins may be used to other side of thepolarizer for the transparent protective film. The transparentprotective film may also contain at least one type of any appropriateadditive. Examples of the additive include an ultraviolet absorbingagent, an antioxidant, a lubricant, a plasticizer, a release agent, ananti-discoloration agent, a flame retardant, a nucleating agent, anantistatic agent, a pigment, and a colorant. The content of thethermoplastic resin in the transparent protective film is preferablyfrom 50 to 100% by weight, more preferably from 50 to 99% by weight,still more preferably from 60 to 98% by weight, particularly preferablyfrom 70 to 97% by weight. If the content of the thermoplastic resin inthe transparent protective film is 50% by weight or less, hightransparency and other properties inherent in the thermoplastic resincan fail to be sufficiently exhibited.

Further an optical film of the invention may be used as other opticallayers, such as a reflective plate, a transflective plate, a retardationplate (a half wavelength plate and a quarter wavelength plate included),an optical compensation film and a viewing angle compensation film,which may be used for formation of a liquid crystal display device etc.These are used in practice as an optical film, or as one layer or twolayers or more of optical layers laminated with polarizing plate.

Although an optical film with the above described optical layerlaminated to the polarizing plate may be formed by a method in whichlaminating is separately carried out sequentially in manufacturingprocess of a liquid crystal display device etc., an optical film in aform of being laminated beforehand has an outstanding advantage that ithas excellent stability in quality and assembly workability, etc., andthus manufacturing processes ability of a liquid crystal display deviceetc. may be raised. Proper adhesion means, such as a pressure-sensitiveadhesive layer, may be used for laminating. On the occasion of adhesionof the above described polarizing plate and other optical layers, theoptical axis may be set as a suitable configuration angle according tothe target retardation characteristics etc.

The pressure-sensitive adhesive layer-carrying optical film of theinvention is preferably used to form various types of image displaydevices such as liquid crystal display devices. Liquid crystal displaydevices may be formed according to conventional techniques.Specifically, liquid crystal display devices are generally formed byappropriately assembling a liquid crystal cell and thepressure-sensitive adhesive layer-carrying optical film and optionallyother component such as a lighting system and incorporating a drivingcircuit according to any conventional technique, except that thepressure-sensitive layer-carrying adhesive optical film of the inventionis used. Any type of liquid crystal cell may also be used such as a TNtype, an STN type, a Π type a VA type and IPS type.

Suitable liquid crystal display devices, such as liquid crystal displaydevice with which the pressure-sensitive adhesive layer-carrying opticalfilm has been located at one side or both sides of the liquid crystalcell, and with which a backlight or a reflective plate is used for alighting system may be manufactured. In this case, the optical film maybe installed in one side or both sides of the liquid crystal cell. Wheninstalling the optical films in both sides, they may be of the same typeor of different type. Furthermore, in assembling a liquid crystaldisplay device, suitable parts, such as diffusion plate, anti-glarelayer, antireflection film, protective plate, prism array, lens arraysheet, optical diffusion plate, and backlight, may be installed insuitable position in one layer or two or more layers.

EXAMPLES

The invention is more specifically described by the examples below,which are not intended to limit the scope of the invention. Themeasurements described below were performed for the evaluation items inthe examples and so on.

Example 1 Preparation of (Meth)acryl-Based Polymer

To a four-neck flask equipped with a stirring blade, a thermometer, anitrogen gas introducing tube, and a condenser were added 80 parts byweight of isodecyl methacrylate (IDM), 20 parts by weight ofN-vinyl-ε-caprolactam (NVP), 10 parts by weight of 2-hydroxybutylacrylate (HEA), 0.1 parts by weight of 2,2′-azobisisobutyronitrile as apolymerization initiator, and 150 parts by weight of ethyl acetate.Nitrogen gas was introduced for 1 hour to replace the air while themixture was gently stirred, and then a polymerization reaction wasperformed for 15 hours while the temperature of the liquid in the flaskwas kept at about 55 to about 60° C. to obtain (meth)acryl-based polymersolution.

To the resulting (meth)acryl-based polymer solution were added 0.5 partsby weight of a trimethylolpropane adduct of xylylene diisocyanate (D110N(trade name) manufactured by Mitsui Chemicals, Inc.) as a crosslinkingagent based on 100 parts by weight of the polymer solid, so that apressure-sensitive adhesive solution was obtained.

The resulting pressure-sensitive adhesive solution was then applied toone side of a silicone-treated, 75-μm-thick, polyethylene terephthalate(PET) film (TORAY ADVANCED FILM Co., LTD., CERAPEEL) so that a25-μm-thick pressure-sensitive adhesive layer could be formed afterdrying. The coating was dried at 130° C. for 3 minutes to form apressure-sensitive adhesive layer, so that a pressure-sensitive adhesivesheet was obtained.

Examples 2 to 13 and Comparative Examples 1 to 11

Pressure-sensitive adhesive sheets were prepared using the process ofExample 1, except that the type and ratio of the monomers used to formthe (meth)acryl-based polymer and the type and content of thecrosslinking agent were changed as shown in Table 1.

Example 14 Preparation of Monomer Component for Use in UV Polymerization

To a four-neck flask were added 39 parts by weight of 2-ethylhexylacrylate (2EHA), 39 parts of isostearyl acrylate (ISA), 18 parts ofN-vinyl-2-pyrrolidone (NVP), 4 parts by weight of 4-hydroxybutylacrylate (HBA), 0.05 parts by weight of each of two photopolymerizationinitiators (IRGACURE 184 (trade name) manufactured by BASF and IRGACURE651 (trade name) manufactured by BASF), so that a monomer mixture wasobtained. Subsequently, the monomer mixture was partiallyphoto-polymerized by being exposed to ultraviolet rays in a nitrogenatmosphere, so that a partial polymer (acryl-based polymer syrup) wasobtained with a conversion of about 10% by weight.

To 100 parts by weight of the above acryl-based polymer syrup) wereadded 0.035 parts by weight of trimethylolpropane triacrylate.Subsequently, these materials were uniformly mixed to form a monomercomponent.

<Production of Pressure-Sensitive Adhesive Layer Using UVPolymerization>

Subsequently, a 38-μm-thick polyester film (Diafoil MRF (trade name)manufactured by Mitsubishi Plastics, Inc.) with its one siderelease-treated with silicone was provided, and the monomer componentprepared as described above was applied to the release-treated surfaceof the polyester film so that a coating layer with a final thickness of100 μm could be formed. Subsequently, a 38-μm-thick polyester film(Diafoil MRE (trade name) manufactured by Mitsubishi Plastics, Inc.)with its one side release-treated with silicone was provided, and thesurface of the applied monomer component was covered with the polyesterfilm in such a manner that the release-treated surface of the film facedthe coating layer. As a result, the coating layer of the monomercomponent was shielded from oxygen. The sheet having the coating layerobtained as described above was irradiated with ultraviolet rays from achemical light lamp (manufactured by TOSHIBA CORPORATION) at anirradiance of 5 mW/cm² (as measured using TOPCON UVR-T1 having a maximumsensitivity at about 350 nm) for 360 seconds, so that the coating layerwas cured to form a pressure-sensitive adhesive layer, and thus apressure-sensitive adhesive sheet was formed. The polyester films placedover both sides of the pressure-sensitive adhesive layer function asrelease liners.

Example 15 to 24

Pressure-sensitive adhesive sheets were prepared using the same processas Example 14, except that the type and ratio of the monofunctionalmonomer, the type and content of the polyfunctional monomer used for thepreparation of monomer component, the thickness of thepressure-sensitive adhesive layer were changed as shown in Table 2.

The pressure-sensitive adhesive sheets (samples) obtained in theexamples and the comparative examples were evaluated as described below.Tables 1 and 2 show the evaluation results.

<Measurement of Gel Fraction>

A predetermined amount (initial weight W1) was sampled from thepressure-sensitive adhesive layer of the pressure-sensitive adhesivesheet. The sample was immersed and stored in an ethyl acetate solutionat room temperature for 1 week. The insoluble matter was then taken outand measured for dry weight (W2). The gel fraction of the sample wasdetermined from the following formula: gel fraction=(W2/W1)×100.

<Dielectric Constant>

Pressure-sensitive adhesive layers (each obtained by peeling off thesilicone-treated PET film from the pressure-sensitive adhesive sheet)were stacked to form an about 100-μm-thick laminate of thepressure-sensitive adhesive layers. The 100-μm-thick and 175-μm-thicksamples obtained by UV Polymerization in Examples 14 to 24 were usedwithout laminating. The laminate of the pressure-sensitive adhesivelayers (or the pressure-sensitive adhesive layer) was sandwiched betweena copper foil and an electrode and then measured for relative dielectricconstant at a frequency of 100 kHz using the instrument shown below.Three samples were prepared, and the average of the measurements for thethree samples was determined as the dielectric constant of the samples.The relative dielectric constant of the pressure-sensitive adhesivelayer at a frequency of 100 kHz was measured under the followingconditions according to JIS K 6911.

Measurement method: capacitance method (instrument: 4294A PrecisionImpedance Analyzer, Agilent Technologies)

Electrode structure: 12.1 mmφ, 0.5 mm thick aluminum plate

Counter electrode: 3 oz copper plate

Measurement environment: 23±1° C., 52±1% RH

<Adhesive Strength>

A 25-μm-thick, PET film (Toray industries Inc., Lumirror S10) was bondedto the pressure-sensitive adhesive surface of the sample obtained ineach of the examples and the comparative examples to form an evaluationsample. The evaluation sample was cut into a piece of 20 mm in width andabout 100 mm in length. The PET film was then peeled off from the samplepiece. The resulting pressure-sensitive adhesive layer was bonded to a0.5 mm thick non-alkali glass plate (1737, manufactured by CorningIncorporated) by a reciprocating motion of a 2 kg roller. After allowedto stand at room temperature (23° C.) for 1 hour, the pressure-sensitiveadhesive layer was measured for peel adhesive strength at a peel angleof 90° and a peel rate of 300 mm/minute.

<Measurement of Haze and Total Light Transmittance>

The pressure-sensitive adhesive sheet obtained in each of the examplesand the comparative examples was bonded to one side of a non-alkaliglass plate with a total light transmittance of 93.3% and a haze of0.1%. The haze and the total light transmittance of the resultinglaminate were measured with a haze meter (MR-100 manufactured byMURAKAMI COLOR RESEARCH LABORATORY). For the measurement with the hazemeter, the pressure-sensitive adhesive sheet was placed on the lightsource side. The haze value of the non-alkali glass, 0.1%, wassubtracted from the measured value when the haze value of thepressure-sensitive adhesive sheet was determined. The measured value wasused as the total light transmittance (%) of the pressure-sensitiveadhesive sheet.

<Change in Haze after Humidification>

A transparent conductive film (a film composed of a 50-μm-thick PET filmand ITO vapor-deposited thereon) was provided. The pressure-sensitiveadhesive layer (obtained by peeling off the silicone-treated PET filmfrom the pressure-sensitive adhesive sheet) was bonded to the surface ofthe transparent conductive film opposite to its surface where the ITOwas vapor-deposited. The resulting pressure-sensitive adhesivelayer-carrying transparent conductive film was bonded to an alkali glassplate with a haze of 0.2% and then held in an autoclave at 50° C. and 5atm for 15 minutes. Subsequently, the haze (H1) of thepressure-sensitive adhesive layer-carrying transparent conductive filmwas measured in such an arrangement that the ITO side of the film wasplaced on the light source side. After the measurement of the haze, thepressure-sensitive adhesive layer-carrying transparent conductive filmwas placed in a humidifying oven at 60° C. and 95% R.H. and stored for250 hours. After the storage, the film was taken out of the oven andallowed to stand at room temperature (23° C.) for 3 hours. The haze (H2)of the pressure-sensitive adhesive layer-carrying transparent conductivefilm was then measured under the same conditions. A change in haze wascalculated by subtracting the haze (H1) from the haze (H2). The resultsare shown in Tables 1 and 2. The change in haze is preferably less than1.5%, more preferably 1.4% or less, even more preferably 1.3% or less.

TABLE 1 Pressure-sensitive adhesive composition (Meth)acryl-Pressure-sensitive Evaluations based polymer Crosslinking adhesive layerTotal light Change in Monomer type and agent Thick- Gel Adhesivetransmit- haze after component ratio Content ness fraction Dielectricstrength tance humidifi- (weight ratio) Type (weight parts) (μm) (%)constant (N/20 mm) Haze (%) cation Example 1 IDM/NVC/HEA = D110N 0.50 2584.7 2.66 7.50 0.3 92.4 0.6 80/20/10 Example 2 IDM/NVC/HEA = D110N 0.2025 75.4 2.75 7.00 0.3 92.2 0.5 80/20/15 Example 3 IDM/NVC/HEA = D110N0.20 25 81.2 2.90 6.80 0.3 92 0.3 80/20/20 Example 4 IDM/NVC/HEA = D110N0.55 25 83.0 2.50 6.88 0.2 92.3 1.1 85/15/10 Example 5 IDM/NVC/HEA =D110N 0.30 25 83.7 2.90 7.50 0.2 92.9 0.9 85/15/15 Example 6 IDM/NVC/HEA= D110N 0.50 25 81.3 3.05 8.02 0.2 92.9 0.8 85/15/20 Example 7IDM/NVC/HEA = D110N 0.15 25 69.6 3.28 12.20 0.2 92.8 0.6 85/15/25Example 8 IDM/NVC/HBA = D110N 0.75 25 77.0 2.36 8.11 0.3 91.9 0.480/20/1 Example 9 IDM/NVC/HBA = D110N 0.20 25 81.5 2.65 8.80 0.3 92.70.2 80/20/10 Example 10 IDM/NVC/HBA = D110N 0.20 25 84.3 2.89 10.20 0.392.7 0.0 80/20/20 Example 11 IDM/NVP/HBA = D110N 0.20 25 80.2 2.75 7.900.3 92.9 1.0 90/10/10 Example 12 LMA/NVC/HBA = D110N 0.50 25 70.0 2.556.90 0.4 92.5 0.6 80/20/10 Example 13 TDMA/NVC/HBA = D110N 0.35 25 70.02.47 5.80 0.4 92.1 0.5 70/30/10 Comparative BA/HBA = D110N 0.50 25 87.95.30 3.21 0.2 93.6 2.0 Example 1 100/3 Comparative i-OA/HBA = D110N 0.5025 76.9 3.57 3.00 0.6 93.5 — Example 2 100/1 Comparative i-AA/HBA =D110N 0.50 25 88.7 4.00 3.65 0.4 93.0 — Example 3 100/1 Comparativei-NA/HBA = D110N 0.50 25 81.9 3.55 2.25 0.8 92.7 2.1 Example 4 100/1Comparative 2EHA/HBA = D110N 0.50 25 79.0 3.70 2.81 0.2 93.0 1.9 Example5 100/1 Comparative BA/LA/HBA = D110N 0.50 25 85.7 3.95 1.02 0.6 93.1 —Example 6 60/40/1 Comparative BA/STA/HBA = D110N 0.50 25 80.9 4.01 1.150.8 93.2 — Example 7 60/40/1 Comparative OA/DA/HBA = D110N 0.50 25 71.13.74 0.50 1.0 93.3 — Example 8 50/50/1 Comparative BA/STA/HBA = D110N0.50 25 80.9 4.01 1.18 0.8 93.2 — Example 9 60/40/1 Comparative2EHA/LA/HBA = D110N 0.50 25 77.6 3.57 1.33 1.0 92.8 — Example 10 55/45/1Comparative 2EHA/NVP/HBA = D110N 0.50 25 82.0 3.21 7.89 2.0 92.1 1.7Example 11 70/30/1

TABLE 2 Pressure-sensitive adhesive composition MonofunctionalPressure-sensitive Evaluations monomer Polyfunctional adhesive layerTotal light Change in Monomer type and monomer Thick- Gel Adhesivetransmit- haze after component ratio Content ness fraction Dielectricstrength tance humidifi- (weight ratio) Type (weight parts) (μm) (%)constant (N/20 mm) Haze (%) cation Example 14 2EHA/ISTA/NVP/HBA = TMPTA0.035 100 86.8 2.93 8.2 0.7 92.3 0.1 39/39/18/4 Example 152EHA/ISTA/NVP/HBA = TMPTA 0.01 100 87.0 3.10 33.0 0.6 92.4 1.238/38/14/10 Example 16 2EHA/ISTA/NVP/HBA = TMPTA 0.035 175 85.7 3.1017.1 0.6 92.4 0.4 49/32/18/1 Example 17 i-NA/ISTA/NVP/HBA = TMPTA 0.01100 78.0 3.11 35.2 0.8 92.2 0.1 47/31/18/4 Example 18 2EHA/ISTA/NVC/HBA= TMPTA 0.035 100 86.1 2.89 6.1 0.5 92.3 1.3 39/39/18/4 Example 192EHA/ISTA/NVP/HBA = TMPTA 0.035 100 89.5 2.90 25.2 0.6 92.4 1.039/39/18/4 Example 20 i-NA/ISTA/NVP/HBA = TMPTA 0.035 100 90.1 2.94 28.80.6 92.3 1.1 39/39/18/4 Example 21 2EHA/IDA/NVC/HBA = TMPTA 0.15 10097.8 3.34 6.5 0.8 92.2 0.3 39/39/18/4 Example 22 2EHA/ISTA/NVP = TMPTA0.035 175 83.8 2.88 18.8 0.7 92.3 0.7 41/41/18 Example 232EHA/ISTA/NVP/HBA = TMPTA 0.035 175 87.3 2.90 20.3 0.6 92.4 0.640.5/40.5/18/1 Example 24 2EHA/ISTA/NVP/HBA = TMPTA 0 175 51.9 2.97 22.20.8 92.3 0.2 39/39/18/4

In Tables 1 and 2, IDM represents isodecyl methacrylate (manufactured byKyoeisha Chemical Co., Ltd., homopolymer Tg=−41° C.);

LMA represents lauryl methacrylate (manufactured by Kyoeisha ChemicalCo., Ltd., homopolymer Tg=−65° C.);

TDMA represents tridecyl methacrylate (manufactured by Sartomer,homopolymer Tg=−40° C.);

ISTA represents isostearyl acrylate (manufactured by Osaka OrganicChemical Industry Ltd., homopolymer Tg=−18° C.);

IDA represents isodecyl acrylate (manufactured by Sartomer, homopolymerTg=−60° C.);

NVC represents N-vinyl-ε-caprolactam (manufactured by BASF);

NVP represents N-vinyl-2-pyrrolidone (manufactured by NIPPON SHOKUBAICO., LTD.);

TMPTA represents trimethylolpropane triacrylate;

i-OA represents isooctyl acrylate (manufactured by Osaka OrganicChemical Industry Ltd., homopolymer Tg=−58° C.);

i-AA represents isoamyl acrylate (manufactured by Kyoeisha Chemical Co.,Ltd., homopolymer Tg=−45° C.);

i-NA represents isononyl acrylate (manufactured by Osaka OrganicChemical Industry Ltd., homopolymer Tg=−58° C.);

2EHA represents 2-ethylhexyl acrylate (manufactured by TOAGOSEI CO.,LTD., homopolymer Tg=−70° C.);

LA represents lauryl acrylate (manufactured by Kyoeisha Chemical Co.,Ltd., homopolymer Tg=−3° C.);

STA represents stearyl acrylate (manufactured by Osaka Organic ChemicalIndustry Ltd., homopolymer Tg=30° C.);

HEA represents 2-hydroxyethyl acrylate;

HBA represents 4-hydroxybutyl acrylate;

BA represents butyl acrylate;

OA represents octyl acrylate;

and DA represents decyl acrylate.

D110N represents a trimethylolpropane adduct of xylylene diisocyanate(D110N (trade name) manufactured by Mitsui Chemicals, Inc.).

DESCRIPTION OF REFERENCE SIGNS

-   -   Reference sign 1 represents a capacitance touch panel;    -   11 represents a decorative panel;    -   12 represents an adhesive layer or an adhesive sheet;    -   13 represents an ITO film;    -   and 14 represents a hard coated film.

1.-19. (canceled)
 20. A pressure-sensitive adhesive sheet, comprising atransparent conductive film as a support and a pressure-sensitiveadhesive layer formed on at least one side of the transparent conductivefilm, wherein the pressure-sensitive adhesive layer is obtained from apressure-sensitive adhesive composition, wherein the pressure-sensitiveadhesive composition comprises a (meth)acryl-based polymer obtained bypolymerization of a monomer component including 30 to 99.5% by weight ofan alkyl (meth)acrylate having an alkyl group of 10 to 18 carbon atomsat an ester end and 0.5 to 50% by weight of a cyclic nitrogen-containingmonomer.
 21. The pressure-sensitive adhesive sheet according to claim20, wherein the alkyl group of the alkyl (meth)acrylate having the alkylgroup of 10 to 18 carbon atoms at the ester end is a branched alkylgroup.
 22. The pressure-sensitive adhesive sheet according to claim 20,wherein the alkyl (meth)acrylate having the alkyl group of 10 to 18carbon atoms at the ester is an alkyl methacrylate having an alkyl groupof 10 to 18 carbon atoms at the ester end.
 23. The pressure-sensitiveadhesive sheet according to claim 20, wherein the alkyl (meth)acrylatehaving the alkyl group of 10 to 18 carbon atoms at the ester is an alkylacrylate having an alkyl group of 10 to 18 carbon atoms at the esterend.
 24. The pressure-sensitive adhesive sheet according to claim 20,wherein the monomer component further includes 0.5% by weight or more ofat least one functional group-containing monomer selected from acarboxyl group-containing monomer, a hydroxyl group-containing monomer,and a cyclic ether group-containing monomer.
 25. The pressure-sensitiveadhesive sheet according to claim 20, wherein the monomer componentfurther includes 0.5% or more by weight of at least one selected from analkyl (meth)acrylate having an alkyl group of 1 to 9 carbon atoms at anester end and an alkyl (meth)acrylate having a cyclic alkyl group at anester end.
 26. The pressure-sensitive adhesive sheet according to claim20, wherein the monomer component further includes 3% or less by weightof a polyfunctional monomer.
 27. The pressure-sensitive adhesive sheetaccording to claim 20, wherein the pressure-sensitive adhesivecomposition comprises 0.01 to 5 parts by weight of a crosslinking agentbased on 100 parts by weight of the (meth)acryl-based polymer.
 28. Thepressure-sensitive adhesive sheet according to claim 20, wherein thepressure-sensitive adhesive layer has a relative dielectric constant of3.5 or less at a frequency of 100 kHz.
 29. The pressure-sensitiveadhesive sheet according to claim 20, wherein the pressure-sensitiveadhesive layer has a gel fraction of 20 to 98% by weight.
 30. Thepressure-sensitive adhesive sheet according to claim 20, wherein thepressure-sensitive adhesive layer has a haze of 2% or less when having athickness of 25 μm.
 31. The pressure-sensitive adhesive sheet accordingto claim 20, wherein the pressure-sensitive adhesive layer has a totallight transmittance of 90% or more.
 32. The pressure-sensitive adhesivesheet according to claim 20, which has an adhesive strength of 0.5 N/20mm or more to alkali glass at a peel angle of 90° and a peel rate of 300mm/minute.